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Proceedings of International Conference on Climate Change, Biodiversity and Ecosystem Services for the Sustainable Development Goals : Policy and Practice 27-29 June 2016 at the Sirindhorn International Environmental Park, Cha-am, Phetchaburi, Thailand

Table  1  Specific  surface  area,  average  pore  diameter  and  total  pore  volume  of  typical  samples  prepared  under  different  hydrothermal  treating  conditions *HT  =  water  hyacinth  treated  hydrothermally  (hydro-char) C  =  HT  carbonized  at  900°C Proceedings  of  the  International  Conference  on  Climate  Change,  Biodiversity  and  Ecosystem  Services  for  the 149 Sustainable  Development  Goals  (SDGs):  Policy  and  Practice  27-29  June  2016,  Cha-am,  Phetchaburi,  Thailand Sample BET of carbonized hydro-char Specific surface area (m2/g) Average pore diameter (nm) Total pore volume (cm3/g) C-HT160 C 8 564.5 3.4 0.481 hours C-HT 180 C 635.8 2.8 0.437 8 hours C-HT 200C 8 hours 470.4 2.1 0.246 C-HT 220 C 8 hours 416.8 2.0 0.205 C-HT 180 C 4 hours 351.9 4.4 0.391 C-HT 180 C 12 hours 359.1 3.7 0.333 improved  surface  properties.  Table  1  summarizes  the  BET  analytical  results  including  specific  surface  area,  average  pore  diameter  and  total  pore  volume  of  each  carbonized  hydro-char  sample.  It  was  found  that  the  hydro-char  sample  which  was  hydrothermally  treated  at  180  for  8  hours  (C-HT  180°C,  8  hours)  possesses  the  highest  specific  surface  area  of  635.8m2/g  with  average  pore  diameter  of  2.8  nm.  These  characteristics  would  suggest  that  the  carbonized  hydro-char  would  have  potential  to  be  utilized  as  carbonaceous  powder  for  fabricating  electrodes  because  of  its  high  specific  surface  area  8. Nevertheless,  confirmation  of  their  carbon  content  would  be  further  conducted  and  discussed  in  the  future.  Therefore,  this  research  attempt  exhibit  a  potential  of  the  conversion  of  water  hyacinth  by  the  hydrothermal  carbonization  method,  as  useful  for  ecosystem  control  activities  by  decreasing  some  environmental  nuisance  as  well  as  providing  functional  carbonaceous  material,  which  would  support  technical  competency  needs  in  the  context  of  the  SDGs. IV.  CONCLUSIONS  Hydrothermal  treatment  could  be  employed  to  convert  dried  water  hyacinth  powder  to  gas,  liquid  and  solid  products  by  hydrolysis  which  could  break  chemical  bonds  with  in  the  cellulosic  structure.  Carbonization  of  hydrothermally  treated  hydro-char  would  further  result  in  remarkable  change  of  physicochemical  properties,  especially  surface  area  of  the  carbonized  hydro- char  which  would  be  confirmed  by  microscopic  and  spectroscopic  analyses.  Based  on  BET  surface  analyses,  the  carbonized  hydro-char  which  was  treated  hydrothermally  at  180°C  for  8  hours  could  exert  the  best  specific  surface  properties  which  would  be  appropriate  for  utilization  as  carbon  electrodes.  This  contribution  suggests  that  conversion  of  water  hyacinth  by  the  hydrothermal  carbonization  method  would  be  useful  for  ecosystem  control  activities  by  reducing  environmental  nuisance  associated  with  the  invasive  and  explosive  growth  of  this  environmental  problem.  In  addition,  the method  provides  a  high  value-added  carbonaceous  material  which  would  support  technical  competency  needs  in  the  context  of  the  SDGs.


Proceedings of International Conference on Climate Change, Biodiversity and Ecosystem Services for the Sustainable Development Goals : Policy and Practice 27-29 June 2016 at the Sirindhorn International Environmental Park, Cha-am, Phetchaburi, Thailand
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